At 180 �C, aspartame undergoes decomposition to form a diketopiperazine derivative.
2.
These are the first diketopiperazine derivatives isolated from a mollusc.
3.
Enzymatic epoxidation of phenylalanine-derived diketopiperazine forms the arene oxide, which undergoes a 6? disrotatory ring opening electrocyclization reaction to produce the uncyclized oxepine.
4.
The original synthesis of spiroligomers allowed for functionalization on the ends of the oligomers, but it did not allow for the incorporation of functionality on the interior diketopiperazine ( DKP ) nitrogens.
5.
While at the University of Missouri, he completed the required classes, wrote his thesis on a new diketopiperazine compound that he had discovered, and worked as a professor in the chemistry department.
6.
Roquefortine C is a cyclodipeptide mycotoxin derived from the diketopiperazine cyclo ( Trp-dehydro-His ) and is a relatively common fungal metabolite produced by a number of " Penicillium " species.
7.
""'Penicillium dipodomyis " "'is a species of the genus of " Penicillium " which occurs in kangaroo rats and produces penicillin and the diketopiperazine dipodazine.
8.
It is an annulated analogue of cyclo ( L-Trp-L-Pro ) which belongs to the most abundant and structurally diverse class of tryptophan-proline 2, 5-diketopiperazine natural products.
9.
Other primary structures of proteins were proposed by various researchers, such as the "'diketopiperazine model "'of Emil Abderhalden and the "'pyrrol / piperidine model "'of Troensegaard in 1942.
10.
Aspartame's major decomposition products are its 2, 5-diketopiperazine, or DKP, form ), the de-esterified dipeptide ( aspartyl-phenylalanine ), and its constituent components, phenylalanine, aspartic acid, and methanol.
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