decalin sentence in Hindi
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- It boils at a lower temperature than its hydrocarbon analog, decalin.
- In chemical terms, it is a formula, a derivative of decalin.
- Further hydrogenation yields decahydronaphthalene or decalin ( ).
- The most popular liquid currently in use is perfluoro-1-methyl decalin.
- For example, decalin is named bicyclo [ 4.4 . 0 ] decane.
- The bicyclic decalin ring system is formed via the eudesmyl cation followed by hydroxylation at C1.
- An amorphous form can be produced by sonochemically reacting molybdenum hexacarbonyl with tellurium dissolved in decalin.
- "' Perfluorodecalin "'( ) is a fluorocarbon, a derivative of decalin in which all of the hydrogen atoms are replaced by fluorine atoms.
- In their 1980 synthesis of reserpine, Paul Wender and coworkers used a Diels Alder reaction to set the cis-decalin framework of the D and E rings of the natural product.
- Rate of polar nucleophilic addition reaction versus 1, 3-dipolar cycloaddition in decalin and in DMSO ( doi : 10.1016 / S0040-4039 ( 00 ) 70991-9)
- The polar reaction, N-cyclo " pen " tenyl pyrrolidine nucleophilic addition to the diazo compound, proceeds 1, 500 times faster in polar DMSO than in non-polar decalin.
- An approach to the " trans "-decalin ring system of salvinorin A has been described by Forsyth ( " et al " . ) utilizing an intramolecular Diels-Alder reaction / Tsuji allylation strategy.
- On the other hand, a close analog of this reaction, N-cyclo " hex " enyl pyrrolidine 1, 3-dipolar cycloaddition to dimethyl diazomalonate, is sped up only 41-fold in DMSO relative to decalin.
- The described synthesis was a relay approach, with the required, heavily functionalized decalin intermediate being made by total synthesis on a small scale, but being derived from the natural product itself for the gram-scale operations required to complete the synthesis.
- The one common atom connecting the participating rings distinguishes spiro compounds from other bicyclics : from " isolated ring compounds " like biphenyl that have no connecting atoms, from " fused ring compounds " like decalin having two rings linked by two adjacent atoms, and from " bridged ring compounds " like norbornane with two rings linked by two non-adjacent atoms.
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